Measuring directly at the affected nucleus

Nuclear Magnetic Resonance

Text about Tc NMR will follow shortly.




More details about theoretical Tc NMR, statistics, etc. will follow shortly.

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Some Recent Publications Involving Technetium NMR

Sawallisch, T. E.; Rupf, S. M.; Abdulkader, A.; Ernst, M. J.; Roca Jungfer, M.;* Abram, U.* [Tc(NO)Cl2(PPh3)2(CH3CN)] and Its Reactions with 2,2’-Dipyridyl Dichalcogenides, Molecules, 2025, 30, 793. DOI: 10.3390/molecules30040793

Ernst, M. J.; Abdulkader, A.; Hagenbach, A.; Claude, G.; Roca Jungfer, M.;* Abram, U.* [Tc(NO)(Cp)(PPh3)Cl] and [Tc(NO)(Cp)(PPh3)(NCCH3)](PF6), and Their Reactions with Pyridine and Chalcogen Donors, Molecules, 2024, 29, 1114. DOI: 10.3390/molecules29051114

Claude, G.; Puccio, D.; Roca Jungfer, M.; Hagenbach, A.; Spreckelmeyer, S.; Abram, U. Technetium Complexes with an Isocyanoalkyne Ligand and Its Reaction Products, Inorg. Chem. 2023, 62, 12445–12452. DOI: 10.1021/acs.inorgchem.3c01638

Roca Jungfer, M.; Abram, U. Unlocking air- and water-stable technetium acetylides and other organometallic complexes, Inorg. Chem. 2022, 61, 7765-7779. DOI: 10.1021/acs.inorgchem.2c00070

Roca Jungfer, M.; Elsholz, L.; Abram, U. Carbonyltechnetium(I) Chemistry with Small Inorganic Ligands, Inorg. Chem. 2022, 61, 2980-2997. DOI: 10.1021/acs.inorgchem.1c03919

Claude, G.; Genz, J.; Weh, D.; Roca Jungfer, M.; Hagenbach, A.; Gembicky, M.; Figueroa, J. S.; Abram, U. Mixed-Isocyanide Complexes of Technetium under Steric and Electronic Control, Inorg. Chem. 2022, 61, 16163-16176. DOI: 10.1021/acs.inorgchem.2c02730

Roca Jungfer, M.; Abram, U. [Tc(OH2)(CO)3(PPh3)2]+: A Synthon for Tc(I) Complexes and its Reactions with Neutral Ligands, Inorg. Chem. 2021, 60, 16734-16753. DOI: 10.1021/acs.inorgchem.1c02599

Roca Jungfer, M.; Elsholz, L.; Abram, U. Technetium Hydrides Revisited: Syntheses, Structures, and Reactions of [TcH3(PPh3)4] and [TcH(CO)3(PPh3)2], Organometallics, 2021, 40, 3095–3112. DOI: 10.1021/acs.organomet.1c00274
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